I ran across messages from three different people on Twitter tweeting about Webroot SecureAnyWhere blocking Google Hangouts in Chrome from working correctly.@WebrootSupport says a solution is being worked on right now.
In the meantime, you can disable the Web Threat Shield ('PC Security' tab > Shields) and Identity Shield ('Identity and Privacy' tab) as you start the Hangout to make it work. (Based on Webroot support's replies)
Solved
FYI: Known issue with WSA and Google Hangouts
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